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KMID : 1059519840280060361
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Journal of the Korean Chemical Society
1984 Volume.28 No. 6 p.361 ~ p.365
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Vibration-Vibration Energy Transfer between H79Br and H81Br
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Lee Chang-Soon
Kim Yoo-Hang
Shin Hyung-Kyu
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Abstract
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The long-lived collision model has been applied to the resonant vibration-vibration energy exchange process H79Br(v = 1) ＋ H81Br(v = 0) → H79Br(v = 0) ＋ H81Br(v = 1) ＋ ΔE = 0.38 cm-1. The energy exchange probabilities have been calculated over the temperature range from 200 to 800K. They show negative temperature dependence (P ∝ T -1.8) and agree with the available experimental data better than those calculated from other theories.
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KEYWORD
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